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Making plastics greener in Swansea

Posted on 08 May 2018 and read 2615 times
Making plastics greener in SwanseaResearchers at the Energy Safety Research Institute (ESRI) (www.esri-swansea.org) at Swansea University have found a way of converting waste CO2 into a molecule that can form the basis of making plastics.

The potential of using global ethylene derived from CO2 is said to be huge, using half a billion tonnes of the carbon emitted each year.

Enrico Andreoli, head of the CO2 utilisation group at ESRI, said: “Considerable research focuses on capturing and storing CO2 emissions, but an alternative to costly long-term storage is to use the captured CO2 as a resource to make useful materials.

“That is why at Swansea we have converted waste CO2 into a molecule called ethylene.

“This is the starting material for the manufacture of detergents, synthetic lubricants, and the vast majority of plastics like polyethylene, polystyrene, and polyvinyl chloride that are essential to modern society.

“Ethylene is currently produced at a very high temperature by steam from cracking oil. We need to find alternative ways of producing it, before we run out of oil.”

The utilisation group uses CO2, water and ‘green’ electricity to generate a sustainable ethylene at room temperature. Central to this process is a new catalyst.

“We have demonstrated that copper and a polyamide additive can be combined to make an excellent catalyst.

“The polyamide doubles the efficiency of ethylene formation, achieving one of the highest rates of conversion ever recorded in standard bicarbonate water solutions.

“The potential for using CO2 to make everyday materials is huge, and it would certainly benefit large-scale producers.

“We are now actively looking for industrial partners interested in helping to take this 21st-century technology forward.”

The research has been published in the American Chemical Society journal ACS Catalysis.